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Shenyang University Of Technology

Physical Chemistry(I)

Shenyang University Of Technology via XuetangX

Overview

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Physical chemistry is a branch or a component part of chemistry. By employing the theories and experimental methods of the basic sciences of physics and mathematics, the task of the physical chemistry lies in studying the principles of equilibrium and rates in chemical reactions including phase and pVT changes, and the relations between those principles and the microscopic structures of substances. It serves as the theoretical basis of the whole chemistry science.

Physical chemistry(I) contains 5 chapters, concerning the theoretical methods on the macroscopic level for studying the principles of equilibrium. Chapter 1 and 2 , The First Law of Thermodynamics, The Second Law of Thermodynamics and the part of Thermodynamics of Multi-component Systems in Chapter 3 elucidate the general equilibrium principles on the macroscopic level. Chapter 4, Chemical Equilibrium and Chapter 5, Phase Equilibrium, including phase diagrams and calculations are two main applications. 



Syllabus

  • Chapter 1 The First Law of Thermodynamics
    • 1-1 State and State Function
    • 1-2 The First Law of Thermodynamics
    • 1-3 Isochoric Heat and Isobaric Heat
    • 1-4 Heat Capacity
    • 1-5 Standard Enthalpy of Phase Transition
    • 1-6 Reversible Process
    • 1-7 Thermochemistry
  • Chapter 2 The Second Law of Thermodynamics
    • 2-1 Statements of the Second Law of Thermodynamics
    • 2-2 Carnot Cycle and Carnot Theorem
    • 2-3 Entropy and Clausius Inequality
    • 2-4 The Calculation of Entropy Changes
    • 2-5 The Standard Molar Reaction Entropy Changes of Chemical Reactions
    • 2-6 The Gibbs and Helmholtz Functions
    • 2-7 The Fundamental Equation of Thermodynamics
    • 2-8 Phase Equlibria of Single-component Systems
  • Chapter 3 Thermodynamics of Multi-component Systems
    • 3-1 Partial Molar Quantities
    • 3-2 Chemical Potential
    • 3-3 Chemical Potential of Gas
    • 3-4 Raoult's Law and Henry's Law
    • 3-5 Mixture of Ideal Liquid
    • 3-6 Ideal Dilute Solution
  • Chapter 4 Chemical Equilibrium
    • 4-1 Direction of Chemical Reaction and Condition of Equilibrium
    • 4-2 Equilibrium Constant Expressions for Gas Reaction
    • 4-3 Calculation of Chemical Equilibrium
    • 4-4 Response of Equilibrium to Conditions
  • Chapter 5 Phase Equilibrium
    • 5-1 Basic Concepts
    • 5-2 Phase Rule
    • 5-3 Phase Diagram of One-component System
    • 5-4 Gas-Liquid Phase Diagram of Two-component Ideal Liquid Mixture System
    • 5-5 Gas-Liquid Phase Diagram of Two-component Real Liquid Mixture System
  • Final Examination

    Taught by

    Zhang Jin, Liu Li, Qiu Li, Zhang Xiao, Zhang Fan, ZhangYu, and LvDan

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