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1. How Do You Know?
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Freshman Organic Chemistry - Structure and Mechanism in Organic Chemistry
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- 1 1. How Do You Know?
- 2 2. Force Laws, Lewis Structures and Resonance
- 3 3. Double Minima, Earnshaw's Theorem and Plum-Puddings
- 4 4. Coping with Smallness and Scanning Probe Microscopy
- 5 5. X-Ray Diffraction
- 6 6. Seeing Bonds by Electron Difference Density
- 7 7. Quantum Mechanical Kinetic Energy
- 8 8. One-Dimensional Wave Functions
- 9 9. Chladni Figures and One-Electron Atoms
- 10 10. Reality and the Orbital Approximation
- 11 11. Orbital Correction and Plum-Pudding Molecules
- 12 12. Overlap and Atom-Pair Bonds
- 13 13. Overlap and Energy-Match
- 14 14. Checking Hybridization Theory with XH_3
- 15 15. Chemical Reactivity: SOMO, HOMO, and LUMO
- 16 16. Recognizing Functional Groups
- 17 17. Reaction Analogies and Carbonyl Reactivity
- 18 18. Amide, Carboxylic Acid and Alkyl Lithium
- 19 19. Oxygen and the Chemical Revolution (Beginning to 1789)
- 20 20. Rise of the Atomic Theory (1790-1805)
- 21 21. Berzelius to Liebig and Wöhler (1805-1832)
- 22 22. Radical and Type Theories (1832-1850)
- 23 23. Valence Theory and Constitutional Structure (1858)
- 24 24. Determining Chemical Structure by Isomer Counting (1869)
- 25 25. Models in 3D Space (1869-1877); Optical Isomers
- 26 26. Van't Hoff's Tetrahedral Carbon and Chirality
- 27 27. Communicating Molecular Structure in Diagrams and Words
- 28 28. Stereochemical Nomenclature; Racemization and Resolution
- 29 29. Preparing Single Enantiomers and the Mechanism of Optical Rotation
- 30 30. Esomeprazole as an Example of Drug Testing and Usage
- 31 31. Preparing Single Enantiomers and Conformational Energy
- 32 32. Stereotopicity and Baeyer Strain Theory
- 33 33. Conformational Energy and Molecular Mechanics
- 34 34. Sharpless Oxidation Catalysts and the Conformation of Cycloalkanes
- 35 35. Understanding Molecular Structure and Energy through Standard Bonds
- 36 36. Bond Energies, the Boltzmann Factor and Entropy
- 37 37. Potential Energy Surfaces, Transition State Theory and Reaction Mechanism
