Chad's Organic Chemistry Videos - Complete Course 2018

Chad's Organic Chemistry Videos - Complete Course 2018

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6.3 The Kinetics of Organic Reactions

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6.3 The Kinetics of Organic Reactions

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Chad's Organic Chemistry Videos - Complete Course 2018

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  1. 1 1.1 Lewis Structures
  2. 2 1.2 Formal Charges
  3. 3 1.3 Valence Bond Theory and Hybridization
  4. 4 1.4 Molecular Orbital Theory
  5. 5 1.5 Polarity
  6. 6 1.6 Intermolecular Forces
  7. 7 2.1 Condensed Structures
  8. 8 2.2 Bond Line Structures
  9. 9 2.3a Resonance
  10. 10 2.3b Resonance and Hybridization
  11. 11 3.1 Introduction to Acids and Bases
  12. 12 3.2 Ranking Bases
  13. 13 3.3 Ranking Acids
  14. 14 4.1a Nomenclature of Alkanes
  15. 15 4.1b Nomenclature of Cycloalkanes
  16. 16 4.1c Systematic Nomenclature of Complex Substituents
  17. 17 4.1d Common Names of Complex Substituents
  18. 18 4.1e Nomenclature of Bicyclic Compounds
  19. 19 4.2 Drawing Constitutional Isomers
  20. 20 4.3 Newman Projections
  21. 21 4.4 Cycloalkanes and Cyclohexane Chair Conformations
  22. 22 5.1 Overview of Isomerism
  23. 23 5.2 Chiral Centers and Chirality
  24. 24 5.3 Absolute Configurations - Assigning R and S
  25. 25 5.4 Molecules with Multiple Chiral Centers
  26. 26 5.5 Fischer Projections
  27. 27 5.6 Determining the Relationship Between a Pair of Molecules
  28. 28 5.7 Amine Inversion and Chiral Molecules Without Chiral Centers
  29. 29 5.8 Optical Activity
  30. 30 6.1 Reaction Enthalpies and Bond Dissociation Energies
  31. 31 6.2 Entropy, Gibbs Free Energy, and the Equilibrium Constant
  32. 32 6.3 The Kinetics of Organic Reactions
  33. 33 6.4 Nucleophiles, Electrophiles, and Intermediates
  34. 34 6.5 Reaction Mechanisms and Curved Arrow Pushing
  35. 35 7.1a Introduction to SN2 Reactions
  36. 36 7.1b Factors Affecting SN2 Reactions
  37. 37 7.2a Introduction to SN1 Reactions
  38. 38 7.2b Carbocation Rearrangements in SN1 Reactions
  39. 39 7.2c Racemization in SN1 Reactions
  40. 40 7.2d Factors Affecting SN1 Reactions
  41. 41 7.3 Unreactivity of Vinyl and Aryl Halides
  42. 42 7.4 Predicting the Products of Substitution Reactions
  43. 43 7.5 Nomenclature of Alkenes
  44. 44 7.6 Stability of Alkenes
  45. 45 7.7a Introduction to E2 Elimination Reactions
  46. 46 7.7b Exceptions to Zaitsev's Rule for E2 Reactions
  47. 47 7.7c The Stereospecificity of E2 Reactions Anti periplanar
  48. 48 7.8 Introduction to E1 Elimination Reactions
  49. 49 7.9 Predicting the Products of Elimination Reactions
  50. 50 7.10 Distinguishing Between Substitution and Elimination Reactions
  51. 51 8.1 Introduction to Alkene Addition Reactions
  52. 52 8.2 Hydrohalogenation
  53. 53 8.3a Hydration Acid Catalyzed Hydration
  54. 54 8.3b Hydration Oxymercuration Demercuration
  55. 55 8.3c Hydration Hydroboration Oxidation
  56. 56 8.4a Acid Catalyzed Addition of an Alcohol
  57. 57 8.4b Alkoxymercuration Demercuration
  58. 58 8.5 Catalytic Hydrogenation
  59. 59 8.6a Halogenation
  60. 60 8.6b Halohydrin Formation
  61. 61 8.7a Anti Dihydroxylation
  62. 62 8.7b Syn Dihydroxylation
  63. 63 8.8 Predicting the Products of Alkene Addition Reactions
  64. 64 8.9 Oxidative Cleavage Ozonolysis and Permanganate Cleavage
  65. 65 9.1 Nomenclature of Alkynes
  66. 66 9.2 Acidity of Alkynes
  67. 67 9.3 Preparation of Alkynes
  68. 68 9.4 Reduction of Alkynes
  69. 69 9.5 Introduction to Addition Reactions of Alkynes
  70. 70 9.6 Hydrohalogenation
  71. 71 9.7 Halogenation
  72. 72 9.8a Acid Catalyzed Hydration
  73. 73 9.8b Hydroboration Oxidation
  74. 74 9.8c Keto Enol Tautomerization
  75. 75 9.9 Ozonolysis
  76. 76 9.10 Alkylation of Acetylide Ions
  77. 77 10.1 Introduction to Free Radical Halogenation
  78. 78 10.2 Free Radical Chlorination vs Bromination
  79. 79 10.3 The Mechanism of Free Radical Halogenation
  80. 80 10.4 Allylic and Benzylic Bromination Using NBS
  81. 81 10.5 Hydrobromination of Alkenes with Peroxide
  82. 82 11.1 Functional Group Conversions
  83. 83 11.2 Increasing the Length of the Carbon Skeleton
  84. 84 11.3 Decreasing the Length of the Carbon Chain or Opening a Ring
  85. 85 11.4a Common Patterns in Synthesis Part 1
  86. 86 11.4b Common Patterns in Synthesis Part 2
  87. 87 11.4c Common Patterns in Synthesis Part 3
  88. 88 11.4d Common Patterns in Synthesis Part 4
  89. 89 12.1 Properties and Nomenclature of Alcohols
  90. 90 12.2 Acidity of Alcohols and Phenols
  91. 91 12.3a Synthesis of Alcohols; Reduction of Ketones and Aldehydes
  92. 92 12.3b Synthesis of Alcohols; Grignard Addition
  93. 93 12.4 Protecting Alcohols
  94. 94 12.5a Reaction with HCl, HBr, and HI
  95. 95 12.5b Substitution with PBr3 and SOCl2
  96. 96 12.5c Formation of Tosylate Esters
  97. 97 12.6 Elimination Dehydration
  98. 98 12.7 Oxidation with Chromic Acid and PCC
  99. 99 13.1 Introduction to Nomenclature of Ethers
  100. 100 13.2 Crown Ethers
  101. 101 13.3 Synthesis and Reactions of Ethers
  102. 102 13.4 Nomenclature of Epoxides
  103. 103 13.5 Synthesis of Epoxides
  104. 104 13.6 Ring Opening of Epoxides
  105. 105 13.7 Nomenclature, Synthesis, and Reactions of Thiols
  106. 106 13.8 Nomenclature, Synthesis, and Reactions of Sulfides
  107. 107 14.1 Introduction to IR Spectroscopy | Organic Chemistry
  108. 108 14.2a IR Spectra of Carbonyl Compounds | Organic Chemistry
  109. 109 14.2b The Effect of Conjugation on the Carbonyl Stretching Frequency | Organic Chemistry
  110. 110 14.3 Interpreting More IR Spectra | Organic Chemistry
  111. 111 14.4 Introduction to Mass Spectrometry | Organic Chemistry
  112. 112 14.5 Isotope Effects in Mass Spectrometry | Organic Chemistry
  113. 113 14.6a Fragmentation Patterns of Alkanes, Alkenes, and Aromatic Compounds | Mass Spectrometry
  114. 114 14.6b Fragmentation Patterns of Alkyl Halides, Alcohols, and Amines | Mass Spectrometry
  115. 115 14.6c Fragmentation Patterns of Ketones and Aldehydes | Mass Spectrometry
  116. 116 15.1 Introduction to NMR | Organic Chemistry
  117. 117 15.2 The Number of Signals in C 13 NMR | Organic Chemistry
  118. 118 15.3 The Number of Signals in Proton NMR | Organic Chemistry
  119. 119 15.4 Homotopic vs Enantiotopic vs Diastereotopic | Organic Chemistry
  120. 120 15.5a The Chemical Shift in C 13 and Proton NMR | Organic Chemistry
  121. 121 15.5b The Integration or Area Under a Signal in Proton NMR | Organic Chemistry
  122. 122 15.5c The Splitting or Multiplicity in Proton NMR | Organic Chemistry
  123. 123 15.6a Interpreting NMR Example 1 | Organic Chemistry
  124. 124 15.6b Interpreting NMR Example 2 | Organic Chemistry
  125. 125 15.6c Interpreting NMR Example 3 | Organic Chemistry
  126. 126 15.6d Structural Determination From All Spectra Example 4 | Organic Chemistry
  127. 127 15.6e Structural Determination From All Spectra Example 5 | Organic Chemistry
  128. 128 15.7 Complex Splitting | NMR | Organic Chemistry
  129. 129 16.1 Introduction to Conjugated Systems and Heats of Hydrogenation
  130. 130 16.2a Introduction to Pi Molecular Orbitals Ethylene
  131. 131 16.2b Pi Molecular Orbitals 1,3 Butadiene
  132. 132 16.2c Pi Molecular Orbitals the Allyl System
  133. 133 16.2d Pi Molecular Orbitals 1,3,5 Hexatriene
  134. 134 16.3 UV Vis Spectroscopy
  135. 135 16.4 Addition Reactions to Conjugated Dienes
  136. 136 16.5a Introduction to Diels Alder Reactions
  137. 137 16.5b Stereoselectivity and Regioselectivity in Diels Alder Reactions
  138. 138 16.5c Diels Alder Reactions with Cyclic Dienes
  139. 139 16.5d Conservation of Orbital Symmetry in Diels Alder Reactions
  140. 140 16.6 Cycloaddition Reactions
  141. 141 16.7 Electrocyclic Reactions
  142. 142 16.8 Sigmatropic Rearrangements
  143. 143 17.1 Nomenclature of Benzenes
  144. 144 17.2a Criteria for Aromatic Compounds
  145. 145 17.2b Aromatic vs Nonaromatic vs Antiaromatic
  146. 146 17.3 The Effects of Aromaticity on SN1 Reactions and Acidity Basicity
  147. 147 17.4 Aromaticity and Molecular Orbital Theory
  148. 148 18.1 Introduction to Aromatic Substitution Reactions
  149. 149 18.2a EAS Bromination and Chlorination
  150. 150 18.2b EAS Sulfonation and Desulfonation
  151. 151 18.2c EAS Nitration
  152. 152 18.2d EAS Friedel Crafts Alkylation and Acylation
  153. 153 18.2e EAS Activating and Deactivating Groups and Ortho Para and Meta Directors
  154. 154 18.2f EAS Predicting the Products of EAS Reactions
  155. 155 18.3 Catalytic Hydrogenation and the Birch Reduction
  156. 156 18.4a Side Chain Oxidation with Permanganate or Chromic Acid
  157. 157 18.4b Benzylic Bromination with NBS
  158. 158 18.4c The Clemmensen and Wolff Kishner Reductions
  159. 159 18.4d Side Chain General Reduction
  160. 160 18.5 Nucleophilic Aromatic Substitution
  161. 161 19.1 Nomenclature of Ketones and Aldehydes
  162. 162 19.2 Synthesis of Ketones and Aldehydes
  163. 163 19.3 Introduction to Nucleophilic Addition Reactions
  164. 164 19.4 Hydration Addition of Water
  165. 165 19.5a Addition of Alcohols
  166. 166 19.5b Cyclic Acetals as Protecting Groups
  167. 167 19.6a Addition of Primary Amines Imine Formation
  168. 168 19.6b Addition of Secondary Amines Enamine Formation
  169. 169 19.6c Mechanism for the Wolff Kishner Reduction
  170. 170 19.7 Reduction via Thioacetals
  171. 171 19.8 Hydride Reduction Reactions
  172. 172 19.9a Addition of Acetylide Ions and Grignard Reagents
  173. 173 19.9b Addition of HCN Cyanohydrin Formation
  174. 174 19.9c The Wittig Reaction
  175. 175 19.10 Baeyer Villiger Oxidation
  176. 176 20.1 Introduction to and Physical Properties of Carboyxylic Acids and Acid Derivatives
  177. 177 20.2a Nomenclature of Carboxylic Acids
  178. 178 20.2b Nomenclature of Acid Halides
  179. 179 20.2c Nomenclature of Acid Anhydrides
  180. 180 20.2d Nomenclature of Esters
  181. 181 20.2e Nomenclature of Amides
  182. 182 20.2f Nomenclature of Nitriles
  183. 183 20.3 Introduction to Nucleophilic Acyl Substitution
  184. 184 20.4 Reaction with Organometallic Reagents
  185. 185 20.5 Hydride Reduction
  186. 186 20.6 Interconversion of Carboxylic Acids and Derivatives
  187. 187 20.7 The Mechanisms of Nucleophilic Acyl Substitution
  188. 188 20.8a Synthesis of Acid Halides
  189. 189 20.8b Reactions of Acid Halides
  190. 190 20.9 Synthesis and Reactions of Acid Anhydrides
  191. 191 20.10a Synthesis of Esters
  192. 192 20.10b Reactions of Esters
  193. 193 20.11 Synthesis and Reactions of Carboxylic Acids
  194. 194 20.12 Synthesis and Reactions of Amides
  195. 195 20.13 Synthesis and Reactions of Nitriles
  196. 196 21.1 Acidity of the Alpha Hydrogen
  197. 197 21.2 General Mechanisms of Alpha Substitution Reactions
  198. 198 21.3a Alpha Halogenation
  199. 199 21.3b The Haloform Reaction
  200. 200 21.3b The HVZ Reaction
  201. 201 21.4a Alpha Alkylation
  202. 202 21.4b The Stork Synthesis
  203. 203 21.5a Introduction to Aldol Reactions
  204. 204 21.5b Mechanisms of Aldol Reactions
  205. 205 21.5c Mixed Aldol Reactions
  206. 206 21.5d Intramolecular Aldol Reactions
  207. 207 21.6a Claisen Condensation Reactions
  208. 208 21.6b Dieckmann Condensation Reactions
  209. 209 21.7a Beta Decarboxylation
  210. 210 21.7b The Malonic Ester Synthesis
  211. 211 21.7c The Acetoacetic Ester Synthesis
  212. 212 21.8 Michael Reactions
  213. 213 21.9 The Robinson Annulation
  214. 214 22.1 Classification of Amines
  215. 215 22.2 Nomenclature of Amines
  216. 216 22.3 Basicity of Amines
  217. 217 22.4a Synthesis of Amines Reduction
  218. 218 22.4b Synthesis of Amines Hofmann Rearrangement
  219. 219 22.4c Synthesis of Amines Curtius Rearrangement and Schmidt Reaction
  220. 220 22.4d Synthesis of Amines Gabriel Synthesis
  221. 221 22.4e Synthesis of Amines Reductive Amination
  222. 222 22.5 Acylation
  223. 223 22.6 Hofmann Elimination
  224. 224 22.7 Cope Elimination
  225. 225 22.8a Reaction with Nitrous Acid and the Sandmeyer Reactions
  226. 226 22.8b Azo Coupling
  227. 227 22.9 EAS Reactions with Nitrogen Heterocycles

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