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Yale University

Alkynes and Conjugation in Allylic Systems and Dienes - Lecture 17

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Overview

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This lecture examines acetylene additions, acidity and isomerization, and the stabilizing effects of allylic conjugation and conjugated dienes. It uses equilibrium constants, reaction rates, regiochemistry, and radical bromination to analyze these organic reactions.

Syllabus

- Chapter 1. Addition to Acetylenes: Regio- and Stereochemistry
.
- Chapter 2. Acidity and Isomerization of Acetylenes
.
- Chapter 3. When Does Conjugation Matter? Allylic Intermediates and Transition States
.
- Chapter 4. Allylic Radicals and Allylic Bromination
.
- Chapter 5. Modest Stabilization of Conjugated Dienes
.

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