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Explore the simulation of electrostatically assembled soft matter systems through this 24-minute conference lecture that examines how composition and interaction parameters influence structural evolution and mechanical properties. Learn about coarse-grained simulation techniques used to study the transition from dispersed constituents to interconnected networks in charged soft matter systems. Discover how researchers identify distinct structural regimes and establish connections between particle dynamics and mechanical response in these complex materials. Gain insights into the fundamental relationship between nanoscale organization and bulk properties in electrostatically assembled soft materials, with applications to understanding hybrid network formation and behavior.