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10. Cation Intermediates. Alkenes: Formation, Addition, and Stability
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Classroom Contents
Freshman Organic Chemistry II
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- 1 1. Mechanism: How Energies and Kinetic Order Influence Reaction Rates
- 2 2. Peculiar Rate Laws, Bond Dissociation Energies, and Relative Reactivities
- 3 3. Rate and Selectivity in Radical-Chain Reactions
- 4 4. Electronegativity, Bond Strength, Electrostatics, and Non-Bonded Interactions
- 5 5. Solvation, H-Bonding, and Ionophores
- 6 6. Brønsted Acidity and the Generality of Nucleophilic Substitution
- 7 7. Nucleophilic Substitution Tools - Stereochemistry, Rate Law, Substrate, Nucleophile
- 8 8. Solvent, Leaving Group, Bridgehead Substitution, and Pentavalent Carbon
- 9 9. Pentavalent Carbon? E2, SN1, E1
- 10 10. Cation Intermediates. Alkenes: Formation, Addition, and Stability
- 11 11. Carbocations and the Mechanism of Electrophilic Addition to Alkenes and Alkynes
- 12 12. Nucleophilic Participation During Electrophilic Addition to Alkenes
- 13 13. Addition to Form Three-Membered Rings: Carbenoids and Epoxidation
- 14 14. Epoxide Opening, Dipolar Cycloaddition, and Ozonolysis
- 15 15. Metals and Catalysis in Alkene Oxidation, Hydrogenation, Metathesis, and Polymerization
- 16 16. Isoprenoids, Rubber, and Tuning Polymer Properties
- 17 17. Alkynes. Conjugation in Allylic Intermediates and Dienes
- 18 18. Linear and Cyclic Conjugation Theory. 4n+2 Aromaticity
- 19 19. Aromatic Transition States: Cycloaddition and Electrocyclic Reactions
- 20 20. Electronic and Vibrational Spectroscopy
- 21 21. Functional Groups and Fingerprints in IR Spectroscopy. Precession of Magnetic Nuclei
- 22 22. Medical MRI and Chemical NMR
- 23 23. Diamagnetic Anisotropy and Spin-Spin Splitting
- 24 24. Higher-Order Effects, Dynamics, and the NMR Time Scale
- 25 25. C-13 and 2D NMR. Electrophilic Aromatic Substitution
- 26 26. Aromatic Substitution in Synthesis: Friedel-Crafts and Moses Gomberg
- 27 27. Triphenylmethyl and an Introduction to Carbonyl Chemistry
- 28 28. Mechanism and Equilibrium of Carbonyl Reactions
- 29 29. Imines and Enamines. Oxidation and Reduction
- 30 30. Oxidation States and Mechanisms
- 31 31. Periodate Cleavage, Retrosynthesis, and Green Chemistry
- 32 32. Measuring Bond Energies: Guest Lecture by Prof. G. Barney Ellison
- 33 33. Green Chemistry. Acids and Acid Derivatives
- 34 34. Acids and Acid Derivatives
- 35 35. Acyl Insertions and [gr]α-Reactivity
- 36 36. [gr]α-Reactivity and Condensation Reactions
- 37 37. Proving the Configuration of Glucose and Synthesizing Two Unnatural Products
- 38 38. Review: Synthesis of Cortisone
