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Thermodynamics - Generalized Analysis of Fluid Properties

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Overview

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This course analyzes the thermodynamic properties of pure, non-ideal fluids. It covers equations of state, fugacity, departure functions, chemical potential, and vapor-liquid and solid-vapor equilibrium using analytical and spreadsheet-based examples.

Syllabus

Exact Differentials & Partial Derivatives.
Maxwell Relations.
State Functions and Maxwell Relations.
Heat Capacity Pressure Dependence.
Three Parameter Equation of State (EOS) Introduction.
Van der Waals Equation of State.
Isothermal Compression of a Non-Ideal Gas.
Isothermal Compression of a Non-Ideal Gas (Spreadsheet).
Real Gas Expansion.
Real Gas Expansion Part 2: Excel Solver.
Roots of Peng-Robinson Equation of State.
Adiabatic Compressor: Non-Ideal Gas.
Peng-Robinson EOS Spreadsheet 1.
Peng-Robinson EOS Spreadsheet 2.
Enthalpy Departure Function for Throttle Feed.
Departure Function: van der Waals Fluid.
VLE in a Constant-Pressure System.
Heat of Vaporization: Clausius-Clapeyron.
Heat of Vaporization: Antoine's Equation.
Gibbs Free Energy Pressure Dependence.
Gibbs Free Energy: T & P Dependence.
Fugacity Introduction.
What is Fugacity?.
Which has the Higher Fugacity?.
Calculate Fugacity of a Fluid.
Steam Fugacity.
Add Liquid to an Evacuated Tank.
Single Component, Solid-Vapor Equilibrium.
Fugacity of a Single Component.
Fugacity Temperature Dependence: Single Component.
Determine Pressure using Peng-Robinson EOS Spreadsheet.
Saturation Pressure from EOS Spreadsheet.
Calculate Fugacity from Equation of State.
Condense Water Vapor from Air.
COSMOtherm: Visualizing Molecular Interactions.
COSMOtherm: Molecular Interactions Probability.
SRK Equation of State Example.
Chemical Potential: Pressure Dependence for Single-Component Part 1.
Chemical Potential: Pressure Dependence for Single-Component Part 2.
Chemical Potential: Pressure Dependence for Single-Component Part 3.
Chemical Potential: Temperature Dependence for Single-Component Part 1.
Chemical Potential: Temperature Dependence for Single-Component Part 2.
Chemical Potential: Temperature Dependence for Single-Component Part 3.
Single-Component Pressure-Temperature Diagram.
Introduction to Nonlinear Regression.
Derivation of Clapeyron and Clausius-Clapeyron Equations.

Taught by

LearnChemE

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