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Organometallic Chemistry - 18 Electron Rule, Metal Carbonyls, and Dinitrogen Complexes

Dr. Prinson P Samuel via YouTube

Overview

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Learn the fundamental principles of organometallic chemistry through this comprehensive lecture series covering essential topics for BSc S5 students following Kerala University curriculum. Master the 18-electron rule and its applications through detailed examples, then explore metal carbonyls including their bonding characteristics and C-O stretching frequencies. Examine the stability of V(CO)6 complexes and discover various preparation methods for carbonyl compounds. Investigate the unique bonding and structural features of ferrocene, a landmark organometallic compound, and conclude with an analysis of dinitrogen complexes and their coordination chemistry. Gain practical understanding of electron counting, molecular orbital theory applications, and structural determination techniques essential for advanced organometallic chemistry studies.

Syllabus

Organometallic Chemistry-Introduction
18 electron rule
18 electron rule examples
Metal carbonyls Part 1
Bonding and C-O stretching frequency in metal carbonyls
stability of V(CO)6
Preparation of carbonyls
Bonding and structure of Ferrocene
Dinitrogen complexes

Taught by

Dr. Prinson P Samuel

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