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Korea Advanced Institute of Science and Technology

Structure of Ceramics: Materials Science Fundamentals

Korea Advanced Institute of Science and Technology via Coursera

Overview

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Ceramic materials power batteries, microchips, and sensors, and their performance traces back to atomic-scale structure. This course connects crystal structure, defect chemistry, and transport into one framework you can apply to real materials. You'll start with close-packed lattices and the rules that explain why ionic crystals form specific structures. From there, you'll use Kröger-Vink notation to describe point defects, build and interpret Brouwer diagrams, and apply the Debye-Hückel correction for charged defects. The course closes with diffusion kinetics and conductivity, plus characterization techniques like Kelvin Probe Force Microscopy and Electrostatic Force Microscopy. Special topics connect theory to devices you use daily, including transistors. In a capstone project, you'll qualify a candidate ceramic electrolyte for a solid oxide fuel cell, producing a Material Qualification Report that ties structure, defect chemistry, and transport together. Who this is for: third- and fourth-year undergraduates in materials science, chemical engineering, physics, or chemistry, plus incoming graduate students and engineers working with oxide materials.

Syllabus

  • Close Packed Lattices
    • You'll learn how atoms pack together in the most efficient arrangements possible. This module covers the geometry of close-packed structures—the building blocks of nearly every ceramic and crystalline material. You'll work through three progressively detailed lessons that build your ability to visualize, describe, and compare packing arrangements in real structures.
  • Stability of Ionic Crystal Structures
    • Not all ionic crystal structures are equally stable. You'll learn what controls structural stability — from ionic radius ratios to charge balance — and how to predict which structure a given ionic compound will adopt. Four detailed lessons give you the tools to reason through stability problems with confidence.
  • Ceramic Crystal Structures
    • You'll connect the foundational principles of packing and stability to specific, real-world ceramic crystal structures. This module also introduces a special topic — the transistor — showing how ceramic structure concepts extend into electronic materials. You'll build the ability to identify and interpret the structures that define ceramic behavior and function.
  • The Brouwer Diagram
    • You'll learn how to track and visualize defect concentrations across a range of conditions using the Brouwer Diagram—a core tool in ceramic materials science. Starting with point defects, you'll build the conceptual and analytical skills to construct and interpret these diagrams for real ceramic systems.
  • Defect Interactions
    • Defects rarely act alone. You'll learn how defects in ceramic materials interact with each other and how those interactions affect material properties. The module also covers the Debye-Hückel correction—a key refinement that accounts for electrostatic interactions between charged defects in real systems.
  • Kelvin Probe Force Microscopy (KPFM) and Electrostatic Force Microscopy (EFM)
    • You'll learn two powerful surface characterization techniques—Kelvin Probe Force Microscopy (KPFM) and Electrostatic Force Microscopy (EFM). This module covers how each technique works, what it measures, and how to interpret the data it produces. You'll build the skills to select and apply these tools when studying the electrical properties of ceramic surfaces.
  • Continuum Diffusion Kinetics
    • You'll learn how atomic transport through ceramic materials is modeled at the continuum scale. This final module covers the governing equations of diffusion kinetics and shows how they apply to real ceramic systems.
  • Project Module: Candidate Electrolyte Material Qualification Report
    • You evaluate a candidate ceramic material being considered for use as a solid oxide fuel cell electrolyte. You justify its crystal structure and stability, model its defect chemistry with a Brouwer diagram, assess the reliability of that model, recommend a surface characterization method, and evaluate its transport behavior. You produce a single Material Qualification Report that integrates structural, defect-chemical, and transport analysis into one engineering recommendation.

Taught by

Seungbum Hong

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